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11.
Carbon Dots (C‐dots) from Cow Manure with Impressive Subcellular Selectivity Tuned by Simple Chemical Modification 下载免费PDF全文
Cintya D'Angelis do E. S. Barbosa Dr. José R. Corrêa Gisele A. Medeiros Gabrielle Barreto Dr. Kelly G. Magalhães Dr. Aline L. de Oliveira Prof. Dr. John Spencer Prof. Dr. Marcelo O. Rodrigues Prof. Dr. Brenno A. D. Neto 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(13):5055-5060
Improved cellular selectivity for nucleoli staining was achieved by simple chemical modification of carbon dots (C‐dots) synthesized from waste carbon sources such as cow manure (or from glucose). The C‐dots were characterized and functionalized (amine‐passivated) with ethylenediamine, affording amide bonds that resulted in bright green fluorescence. The new modified C‐dots were successfully applied as selective live‐cell fluorescence imaging probes with impressive subcellular selectivity and the ability to selectively stain nucleoli in breast cancer cell lineages (MCF‐7). The C‐dots were also tested in four other cellular models and showed the same cellular selection in live‐cell imaging experiments. 相似文献
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Elisa Martinelli Elisa Guazzelli Cristina Bartoli Matteo Gazzarri Federica Chiellini Giancarlo Galli Maureen E. Callow James A. Callow John A. Finlay Sophie Hill 《Journal of polymer science. Part A, Polymer chemistry》2015,53(10):1213-1225
Well‐defined amphiphilic pentablock copolymers Siy‐(EGx‐FAz)2 composed of polysiloxane (Si), polyethylene glycol (EG), and perfluorohexylethyl polyacrylate (FA) blocks are synthesized by ATRP of FA monomer starting from a difunctional bromo‐terminated macroinitiator. Diblock copolymers EGx‐FAz are also synthesized as model systems. The block copolymers are used, either alone or blended with a PDMS matrix in varied loadings, to prepare antibiofouling coatings. Angle‐resolved XPS and contact angle measurements show that the coating surface is highly enriched in fluorine content but undergoes reconstruction after contact with water. Protein adsorption experiments with human serum albumin and calf serum highlight that diblock copolymers resist protein adhesion better than do pentablock copolymers. Blending of the pentablock copolymer with PDMS results in increased protein adsorption. By contrast, the PDMS‐matrix coatings show high removal percentages of sporelings of the green fouling alga Ulva linza. © 2015 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 2015 , 53, 1213–1225 相似文献
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John Bamberg S.P. Glasby Luke Morgan Alice C. Niemeyer 《Journal of Pure and Applied Algebra》2019,223(12):5428-5429
We give a correction to Fig. 1 and supporting text published in the paper: ‘Maximal linear groups induced on the Frattini quotient of a p-group’, J. Pure Appl. Algebra 222 (10) (2018) 2931–2951. 相似文献
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We classify the trees on vertices with the maximum and the minimum number of certain generalized colorings, including conflict-free, odd, non-monochromatic, star, and star rainbow vertex colorings. We also extend a result of Cutler and Radcliffe on the maximum and minimum number of existence homomorphisms from a tree to a completely looped graph on vertices. 相似文献
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Dr. Sevan D. Houston Dr. Hui Xing Prof. Paul V. Bernhardt Timothy J. Vanden Berg Dr. John Tsanaktsidis Dr. G. Paul Savage Prof. Craig M. Williams 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(11):2735-2739
The scope and limitations of Eaton's rhodium(I)-catalyzed valence isomerization of cubane to cyclooctatetraene (COT) were investigated in the context of functional group tolerability, multiple substitution modes and the ability of cubane-alcohols to undergo one-pot tandem Ley–Griffith Wittig reactions in the absence of a transition metal catalyst. 相似文献
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Fourier transform infrared (FTIR) smog chamber techniques were used to investigate the atmospheric chemistry of the isotopologues of methane. Relative rate measurements were performed to determine the kinetics of the reaction of the isotopologues of methane with OH radicals in cm3 molecule−1 s−1 units: k(CH3D + OH) = (5.19 ± 0.90) × 10−15, k(CH2D2 + OH) = (4.11 ± 0.74) × 10−15, k(CHD3 + OH) = (2.14 ± 0.43) × 10−15, and k(CD4 + OH) = (1.17 ± 0.19) × 10−15 in 700 Torr of air diluent at 296 ± 2 K. Using the determined OH rate coefficients, the atmospheric lifetimes for CH4–xDx (x = 1–4) were estimated to be 6.1, 7.7, 14.8, and 27.0 years, respectively. The results are discussed in relation to previous measurements of these rate coefficients. 相似文献
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